Theme:  Si- & Li Metal-Based Anodes: Pushing What is Possible.

When:  Friday, January 24, 2025 from 9:00am until 5:30pm.

Where:  A. James Clark Hall Forum, 8278 Paint Branch Dr, College Park, MD 20742.

Cost: Lunch & afternoon break service will be provided for all who register by Noon (EDT) on January 17, 2025.  Late registrants may dine at on-campus (IDEA Factory, Stamp Student Union, or Iribe Cafe) or at one of the Baltimore Avenue (Route 1) restaurants a short walk from campus.

Registration:  Online registration link: 

Agenda TBD

Catered Lunch provided by Magnera

Speakers: 

  • Daniel Abraham, Argonne National Laboratory
  • Paul Albertus, University of Maryland
  • Rob Anstey,Graphenix Development Inc (GDI)
  • Brian Cunningham, Department of Energy
  • Ram Manthiram, University of Texas at Austin
  • Amy Marschilok or Esther Takeuchi, Stony Brook University
  • Nathan Neale, National Renewable Energy Laboratory
  • Paul Schisselbauer, Lyten
  • Ionel Stefan, Amprius
  • Gabriel Veith, Oak Ridge National Laboratory
  • Eric Wachsman, University of Maryland
  • Chunsheng Wang, University of Maryland

Planning to attend in person?  Please note: There are three airports that service the Baltimore/Washington D.C. region (Dulles, Reagan National and BWI).

Parking on campus can be a bit tricky, however, policies are a bit more relaxed during the summer!

  • Follow this link to the UMD DOTS website to learn more about parking, and how to avoid pesky citations. 
  • You may download a visitor parking map here. Note: The Xfinity visitor parking is the closest to  A. James Clark Hall.
  • Daniel Abraham, Argonne National Laboratory
  • Paul Albertus, University of Maryland
  • Rob Anstey,Graphenix Development Inc (GDI)
  • Brian Cunningham, Department of Energy
  • Impact of Chemical Crossover in Lithium-ion Cells with Silicon Anode (Ram Manthiram, University of Texas at Austin)

Chemical crossover between electrodes plays a critical role in the performance of lithium-ion cells. While the detrimental impact of crossover from layered oxide cathodes to graphite anode is well known in the literature, the impact of such crossover in cells comprised of high-nickel cathodes and silicon anodes is not fully understood or established. Furthermore, the anode to cathode crossover in such cells needs to be understood as well. This presentation will focus on the understanding developed on such crossovers in cells with high-nickel cathodes and silicon anodes, employing in-depth electrochemical measurements and advanced characterization methodologies.

  • Amy Marschilok or Esther Takeuchi, Stony Brook University
  • Nathan Neale, National Renewable Energy Laboratory
  • Paul Schisselbauer, Lyten
  • Ionel Stefan, Amprius
  • Gabriel Veith, Oak Ridge National Laboratory
  • High-Rate Li-Metal Anodes in Solid-State Batteries by Tailored Materials, Structures, and Interfaces (Eric Wachsman)

Oxide-based solid-state Li-batteries (SSLiBs) have the potential to be a transformational and intrinsically safe energy storage solution due to their non-flammable ceramic electrolyte that enables the use of high-capacity Li metal anodes and high voltage cathodes for higher energy density over a much wider operating temperature range. However, their progress has been limited due to electrode/electrolyte interfacial issues. In particular for Li-metal anodes concerns over dendrite formation/propagation and the requirement for elevated temperature and high stack pressure are still prevalent. To eliminate these concerns a rational design of tailored materials, structures, and interfaces in Li-metal anodes will be presented. In addition, demonstration of high-rate Li metal cycling, achieving 100 mA/cm 2 at room temperature with no applied pressure, and progress toward full cells using these tailored materials, structures, and interfaces will be presented.

  • Low-Temperature Electrolytes for MicroSi-based Li-ion batteries (Chunsheng Wang)

Silicon anodes offer lower cost and higher capacity than graphite in Li-ion batteries. However, they suffer from fast capacity decay and low Coulombic efficiency in carbonate electrolytes. Using nano-sized alloying anodes can enhance the cell cycle life but also reduce the battery calendar life and increase manufacturing costs. We developed electrolytes that enable micro-sized Si anodes to achieve a long cycle life in a wide temperature range from -40oC to +40oC at lean electrolytes without electrode swelling due to the formation of LiF-rich inorganic SEI on Si. The electrolytes also enable the micro-Si||NMC811 full cells to achieve high performance in wide temperatures.   

 

  • Daniel Abraham, Argonne National Laboratory
  • Paul Albertus, University of Maryland
  • Rob Anstey,Graphenix Development Inc (GDI)
  • Brian Cunningham, Department of Energy
  • Ram Manthiram, University of Texas at Austin

Arumugam Manthiram is the George T. and Gladys H. Abell Endowed Chair of Engineering at the University of Texas at Austin. He has authored more than 1,000 journal articles and 22 issued patents with 125,000 citations and an h-index of 172. Manthiram has mentored close to 300 students and postdoctoral researchers, including the graduation of 76 Ph.D. students. He delivered the 2019 Chemistry Nobel Prize Lecture on behalf of Professor John Goodenough.

  • Amy Marschilok or Esther Takeuchi, Stony Brook University
  • Nathan Neale, National Renewable Energy Laboratory
  • Paul Schisselbauer, Lyten
  • Ionel Stefan, Amprius
  • Gabriel Veith, Oak Ridge National Laboratory
  • Eric Wachsman, University of Maryland

Eric Wachsman is a Distinguished University Professor at the University of Maryland with appointments in the Departments of Materials Science and Engineering (MSE) and Chemical and Biomolecular Engineering (CHBE). He is also the Director of the Maryland Energy Innovation Institute and Past President of The Electrochemical Society. His research is focused on solid ion-conducting materials and electrocatalysts, including solid state batteries, solid oxide fuel cells and electrolysis cells and ion-transport membranes.

  • Chunsheng Wang, University of Maryland

Chungsheng Wang, is a Professor of Chemical & Biomolecular Engineering at the University of Maryland, and the Director of the Center for Research in Extreme Batteries. Wang's current research activities include rechargeable batteries, applied electrochemistry, fuel cells, electroanalytical technologies, nanostructured materials, electrochemical gas separation and compression.


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